A new mechanism for hydrogen activation! A new mechanism for hydrogen activation! Hydride rebound: an FLP-like cooperative mechanism for H2 activation by a potassium aluminyl compound K. M. Byrne, J. Hicks, L. P. Griffin, S. Aldridge, T. Krämer Chem.-Eur. J. 2025, in press DOI: 10.1002/chem.202500095
Metathesis involving B=N bonds Metathesis involving B=N bonds Metathesis chemistry of inorganic cumulenes driven by B-O bond formation J. Tang, C. Hu, A. E. Crumpton, D. Sarkar, L. P. Griffin, J. M. Goicoechea, S Aldridge Chem. Sci. 2024, in press DOI: 10.1039/D4SC07487D
Inorganic Cumulenes! Inorganic Cumulenes! Synthesis, geometric and electronic structures of inorganic cumulenes J. Tang, C. Hu, A. E. Crumpton, D. Sarkar, L. P. Griffin, M. Dietz, J. M. Goicoechea, S. Aldridge J. Am. Chem. Soc. 2024, 146, 30778-30783 DOI: 10.1021/jacs.4c13231
Metal-metal bond formation using diboron reductants Metal-metal bond formation using diboron reductants Zinc borylation and reduction by a diborane(4) species via B-O bond formation L. P. Griffin, S. Aldridge Chem. Sci. 2024, 15, 19577-19582 DOI: 10.1039/D4SC06389C